2024

• TM-catalyzed reaction

  Stereospecific and Stereodivergent Allyl-Allyl Coupling: Construction of Vicinal Tertiary and All-Carbon Quaternary Stereocenters

  Yongsuk Jung+, Jieun Kim+, Gwanggyun Kim, Jiyeon Ko, Sungwoo Hong*, and Seung Hwan Cho* (+These authors contributed equally to this work) 

  ACS Catal. Accepted.

  

• TM-catalyzed reaction

  Copper-Catalyzed Regio-, Diastereo- and Enantioselective Allylic Alkylation with 1,1-Diborylalkanes

  Minjae Kim, Gwanggyun Kim, Doyoon Kim, Seung Hwan Cho* 
  in revison.

2023

• TM-catalyzed reaction

  Iridium-Catalyzed Chemo-, Diastereo-, and Enantioselective Allyl–Allyl Coupling: Accessing All Four Stereoisomers of (E)-1-Boryl-Substituted 1,5-Dienes by Chirality Pairing

  Yongsuk Jung+, Seok Yeol Yoo+, Yonghoon Jin, Jaehyun Yu, Seungcheol Han, Jeongwoo Yu, Yoonsu Park,* Seung Hwan Cho* (+These authors contributed equally to this work) 

  Angew. Chem., Int. Ed. 2023, 62, e202218794. 

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2022

2021

• TM-catalyzed reaction

  Copper-Catalyzed Enantiotopic-Group-Selective Allylation of gem-Diborylalkanes

  Minjae Kim+, Bohyun Park+, Minkyeong Shin, Suyeon Kim, Junghoon Kim, Mu-Hyun Baik,* Seung Hwan Cho* (+These authors contributed equally to this work)
  J. Am. Chem. Soc. 2021, 143, 1069-1077.
  Highlighted in Synfacts, 2021, 17, 0292. 

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• TM-catalyzed reaction

  Pd‐Catalyzed Negishi Cross‐Coupling of Vinyl Bromides with Diborylmethylzinc Chlorides

  Minjae Kim, Jun Hee Lee,* Seung Hwan Cho* 

  Bull. Kor. Chem. Soc. 2021, 42, 499-501.
  [Special issue on "Chemical Synthesis & Reaction Development"] 

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2020

• TM-catalyzed reaction

  Facile Synthesis of a-Boryl-Substituted Allylboronate Esters Using Stable 1,1-Bis[(pinacolato)boryl]methylzinc Halides

  Minkyeong Shin, Minjae Kim, Chiwon Hwang, Hyojae Lee, Hyunchul Kwon, Jinyoung Park, Eunsung Lee, Seung Hwan Cho* 

  Org. Lett. 2020, 22, 2476-2480. 

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2019

• TM-catalyzed reaction

  Copper-Catalyzed Diastereo- and Enantioselective Addition of 1,1-Diborylalkanes to Cyclic Ketimines and α-Imino Esters

  Jeongho Kim, Minkyeong Shin, Seung Hwan Cho*  

  ACS Catal. 2019, 9, 8503-8508. 
  Highlighted in Synfacts, 2019, 15, 1281. 

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• TM-catalyzed reaction

  Palladium-Catalyzed Chemoselective Negishi Cross-Coupling of Bis[(pinacolato)boryl]methyl Zinc Halides with Aryl (Pseudo)Halides

  Hyojae Lee, Yeosan Lee, Seung Hwan Cho* 

  Org. Lett. 2019, 21, 5912-5916. 

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• TM-catalyzed reaction

  Chemoselective Palladium-Catalyzed Suzuki-Miyaura Cross-Coupling of (Diborylmethyl)silanes with Alkenyl Bromides

  Junghoon Kim, Eunsung Lee, Seung Hwan Cho* 

  Asian J. Org. Chem. 2019, 8, 1664-1667.
  [Special issue on "Researchers in Korea"] 

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• TM-catalyzed reaction

  Access to Enantioenriched Benzylic 1,1-Silylboronate Esters by Palladium-Catalyzed Enantiotopic-Group Selective Suzuki-Miyaura Coupling of (Diborylmethyl)silanes with Aryl Iodides

  Junghoon Kim, Seung Hwan Cho* 

  ACS Catal. 2019, 9, 230-235. 

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• TM-catalyzed reaction

  Improved Synthesis of β-Aminoboronate Esters via Copper-Catalyzed Diastereo- and Enantioselective Addition of 1,1-Diborylalkanes to Acyclic Arylaldimines

  Jeongho Kim,+ Chiwon Hwang,+ Youngmin Kim, Seung Hwan Cho* (+ These authors contribute equally to this work) 

  Org. Process Res. Dev. 2019, 23, 1663-1668.
  [Special issue on "Honoring 25 Years of the Buchwald-Hartwig Amination"] 

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2018

• TM-catalyzed reaction

  Generation and Application of (Diborylmethyl)zinc(II) Species: Access to Enantioenriched gem-Diborylalkanes by an Asymmetric Allylic Substitution” Angew. Chem., Int. Ed. 2018, 57, 12930-12934

  Yeosan Lee, Jinyoung Park, Seung Hwan Cho* 

  Angew. Chem., Int. Ed. 2018, 57, 12930-12934.
  Highlighted in Synfacts, 2018, 14, 1164. 

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2017

• TM-catalyzed reaction

  Diastereo- and Enantioselective Synthesis of b-Aminoboronate Esters by Copper(I)-Catalyzed 1,2-Addition of 1,1-Bis[(pinacolato)boryl]alkanes to Imines

  Jeongho Kim, Kwangwook Ko, Seung Hwan Cho* 

  Angew. Chem., Int. Ed. 2017, 56, 11584-11588.
  Highlighted in Synfacts, 2017, 13, 959. 

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2016

• TM-catalyzed reaction

  Copper-Catalyzed Diastereoselective Addition of Diborylmethane to N–tert-butanesulfinyl Aldimines: Synthesis of b-Aminoboronates

  Jinyoung Park, Yeosan Lee, Junghoon Kim, Seung Hwan Cho* 

  Org. Lett. 2016, 18, 1210-1213.
  Highlighted in Synfacts, 2016, 12, 503. 

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• TM-catalyzed reaction

  Synthesis of Branched Alkylboronates by Copper-Catalyzed Allylic Substitution Reactions of Allylic Chlorides with 1,1-Diborylalkanes

  Junghoon Kim, Sangwoo Park, Jinyoung Park, Seung Hwan Cho* 

  Angew. Chem., Int. Ed. 2016, 55, 1498-1501. 

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BEFORE 2016