2023

• TM-free reaction

  Anion-Mediated, Stereospecific Synthesis of Secondary and Tertiary Cyclopropylboronates from Chiral Epoxides and gem-Diborylalkanes

  Gwanggyun Kim+, Minjae Kim,+ Changsu Ryu, Juhyeok Choi, Seung Hwan Cho* (+These authors contributed equally to this work) 

  Org. Lett. 2023, 25, 4130-4134. 

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• TM-catalyzed reaction

  Iridium-Catalyzed Chemo-, Diastereo-, and Enantioselective Allyl–Allyl Coupling: Accessing All Four Stereoisomers of (E)-1-Boryl-Substituted 1,5-Dienes by Chirality Pairing

  Yongsuk Jung+, Seok Yeol Yoo+, Yonghoon Jin, Jaehyun Yu, Seungcheol Han, Jeongwoo Yu, Yoonsu Park,* Seung Hwan Cho* (+These authors contributed equally to this work) 

  Angew. Chem., Int. Ed. 2023, 62, e202218794. 

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• TM-free reaction

  Chemo-, Regio-, and Stereoselective Access to (E)-Boryl-Substituted Allyl Fluorides via Electrophilic Fluorodesilylation

  Yongsuk Jung, Seung Hwan Cho* 

  Synlett 2023, 34, 2165-2168. 

  [Special issue on “Modern Organoboron Chemistry: 60 Years of the Matteson Reaction”]​

  Highlighted in Organic Chemistry Portal

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